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A tetrakis(piperidine)-complex of iridium(III) Two new salts of hexachloroiridate(III)

โœ Scribed by E.R. Birnbaum

Book ID
118907670
Publisher
Elsevier Science
Year
1969
Weight
281 KB
Volume
31
Category
Article
ISSN
0022-1902

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Complexes containing hydrogen and an olefin bonded to the same metal atoms have been postulated as unstable intermediates in varioue catalytic reactions e.g. CXO syntheses (l), but have not hitherto been prepared. We now describe a hydrido cycle-octa-1,5-diene complex of iridium(II1) CI~c12(C#,2)12