The title compound, [Pd(CH 3 )Cl(C 5 H 5 N) 2 ], has been synthesized by the reaction of [PdMeCl(COD)] (COD is 1,5cyclooctadiene) with pyridine in dichloromethane; it is square-planar. The crystal structure features dipole-dipole and stacking interactions.
trans-Dichlorodipyridinepalladium(II)
✍ Scribed by Liao, Chuang-Yi ;Lee, Hon Man
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 80 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the structure of the title compound, [PdCl~2~(C~5~H~5~N)~2~], determined at 150 K, the Pd atom is located on an inversion centre. The structure is a polymorph of a previously reported structure [Viossat et al. (1993). Acta Cryst. C49, 84–85].
📜 SIMILAR VOLUMES
In the title compound, [PdCl 2 {(5-C 4 H 4 N)(5-C 5 H 5 )Fe} 2 ], the Pd II atom lies on an inversion center in a slightly distorted square-planar arrangement of cis Cl and N ligands. The azaferrocene ligands display a typical sandwich structure with practically parallel Cp and pyrrolyl rings. Weak
The structure of the title compound, [PdCl 2 (C 10 H 10 N 2 ) 2 ], has the palladium center situated on a center of inversion. The imidazole group is twisted from the square coordination plane with a C-N-Pd-Cl torsion angle of 31.93 (12) ; this is different from the angle reported in closely related
In the title compound, __trans__-[PdCl~2~{P(C~7~H~7~)~3~}~2~], where P(C~7~H~7~)~3~ is tri-__m__-tolylphosphine, the Pd atom is on an inversion centre, resulting in a __trans__-square-planar geometry. Selected geometric parameters are Pd—P and Pd—Cl distances of 2.3289 (4) and 2.2897 (4) Å, respecti