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trans-Chloro­methyl­dipyridine­palladium(II)

✍ Scribed by Owen, Gareth R. ;Haddow, Mairi F.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
218 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Pd(CH 3 )Cl(C 5 H 5 N) 2 ], has been synthesized by the reaction of [PdMeCl(COD)] (COD is 1,5cyclooctadiene) with pyridine in dichloromethane; it is square-planar. The crystal structure features dipole-dipole and stacking interactions.


📜 SIMILAR VOLUMES


trans-Dichloro­dipyridine­palladium(II)
✍ Liao, Chuang-Yi ;Lee, Hon Man 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 80 KB

In the structure of the title compound, [PdCl~2~(C~5~H~5~N)~2~], determined at 150 K, the Pd atom is located on an inversion centre. The structure is a polymorph of a previously reported structure [Viossat __et al.__ (1993). __Acta Cryst__. C**49**, 84–85].

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.032 wR factor = 0.084 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.009 A Ê Some non-H atoms missing Disorder in main residue R factor = 0.046 wR factor = 0.120 Data-to-parameter ratio = 17.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.