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trans-Di­aqua­bis­[2-(2-pyridyl)­ethanol-κ2N,O]­zinc(II) disaccharinate

✍ Scribed by Hamamci, Sevim ;Yilmaz, Veysel T. ;Thöne, Carsten


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
319 KB
Volume
58
Category
Article
ISSN
1600-5368

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trans-Di­aqua­bis(2-pyridyl­ethanol-N,O)
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The title complex, [Ni(pyet) 2 (H 2 O) 2 ](sac) 2 (sac À is the saccharinate anion, C 7 H 4 NO 3 S À , and pyet is 2-pyridylethanol, C 7 H 9 NO), is built of discrete sac À and [Ni(H 2 O) 2 (pyet) 2 ] 2+ ions. The Co 2+ ion sits on a centre of symmetry and exhibits a distorted octahedral geometry, f

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✍ Gryz, Michał ;Starosta, Wojciech ;Leciejewicz, Janusz 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.113 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(2-chlorobenzoato-κ2O,O′)bis[methyl N
✍ Maroszová, Jaroslava ;Findoráková, Lenka ;Györyvá, Katarína ;Moncol, Jan ;Melník 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 333 KB

In the title compound, [Zn(C 7 H 4 ClO 2 ) 2 (C 7 H 8 N 2 O 2 ) 2 ], the Zn II ion is coordinated by two N atoms from two methyl N-(3pyridyl)carbamate ligands and four O atoms from two bidentate 2-chlorobenzoate anions in a pseudo-octahedral geometry. The Zn-O distances are in the range 2.0484 (16)-