The title complex, [Ni(pyet) 2 (H 2 O) 2 ](sac) 2 (sac À is the saccharinate anion, C 7 H 4 NO 3 S À , and pyet is 2-pyridylethanol, C 7 H 9 NO), is built of discrete sac À and [Ni(H 2 O) 2 (pyet) 2 ] 2+ ions. The Co 2+ ion sits on a centre of symmetry and exhibits a distorted octahedral geometry, f
trans-Diaquabis[2-(2-pyridyl)ethanol-κ2N,O]zinc(II) disaccharinate
✍ Scribed by Hamamci, Sevim ;Yilmaz, Veysel T. ;Thöne, Carsten
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 319 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.113 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Zn(C 7 H 4 ClO 2 ) 2 (C 7 H 8 N 2 O 2 ) 2 ], the Zn II ion is coordinated by two N atoms from two methyl N-(3pyridyl)carbamate ligands and four O atoms from two bidentate 2-chlorobenzoate anions in a pseudo-octahedral geometry. The Zn-O distances are in the range 2.0484 (16)-