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trans-Di­aqua­bis(2-pyridyl­ethanol-N,O)­cobalt(II) disaccharinate

✍ Scribed by Yilmaz, Veysel T. ;Hamamci, Sevim ;Thöne, Carsten

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
316 KB
Volume
58
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

trans-Di­aqua­bis(2-pyridyl­ethanol-N,O)
trans-Di­aqua­bis(2-pyridyl­ethanol-N,O)­nickel(II) disaccharinate
✍ Hamamci, Sevim ;Yilmaz, Veysel T. ;Thöne, Carsten 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 317 KB

The title complex, [Ni(pyet) 2 (H 2 O) 2 ](sac) 2 (sac À is the saccharinate anion, C 7 H 4 NO 3 S À , and pyet is 2-pyridylethanol, C 7 H 9 NO), is built of discrete sac À and [Ni(H 2 O) 2 (pyet) 2 ] 2+ ions. The Co 2+ ion sits on a centre of symmetry and exhibits a distorted octahedral geometry, f

trans-Bis(aniline-κN)dichloro­bis(ethano
trans-Bis(aniline-κN)dichloro­bis(ethanol-κO)cobalt(II)
✍ Clegg, William ;Martin, Nicola C. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

The title compound, [CoCl~2~(C~6~H~7~N)~2~(C~2~H~6~O)~2~], was obtained unintentionally as the product of an attempted synthesis of a polycarboxylate-bridged network complex of cobalt(II) using aniline as a base to deprotonate the organic acid. The molecule is centrosymmetric, so pairs of equivalent