Trans-cis photoisomerization of para-styrylstilbenes
β Scribed by Yoshikatsu Ito; Yoshihiro Uozu; Teruo Matsuura
- Book ID
- 108383007
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 229 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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Unirnolecular dissociation of Arz into Ari was investigated with a double focusing sector field mass spectrometer. Ar; was produced by electron impact ionization of Ar3 formed by nozzle expansion. It was found that the m&stable dissociation rate is strongly dependent on the sragnation gas temperatur
Usmg nummal baus sets, the ~omc and dua&cal evmted states of the twisted styrcnc n~olccule have been calculated through extended Cl, after appropriate XT procedures The lowest ekclted state IS a duadlcal, and the photolsomerlzatlon should not involve the ,OIUC state.