## Abstract The __transโcis__ isomerization of the styrylpyridine carbonโcarbon double bond induced by visible light irradiation in __fac__โ[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2โฒโbipyridine; stpy = __t__โ4โstyrylpyridine) has been investigated by means of quantumโchemical methods. The structures
Charge transfer and cis-trans photoisomerization
โ Scribed by Ebbesen, T. W.; Tokumaru, K.; Sumitani, M.; Yoshihara, K.
- Book ID
- 121004468
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 629 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Usmg nummal baus sets, the ~omc and dua&cal evmted states of the twisted styrcnc n~olccule have been calculated through extended Cl, after appropriate XT procedures The lowest ekclted state IS a duadlcal, and the photolsomerlzatlon should not involve the ,OIUC state.
Unirnolecular dissociation of Arz into Ari was investigated with a double focusing sector field mass spectrometer. Ar; was produced by electron impact ionization of Ar3 formed by nozzle expansion. It was found that the m&stable dissociation rate is strongly dependent on the sragnation gas temperatur