Trans-cis photoisomerization of meta-(phenylazo)azobenzenes
β Scribed by Yoshikatsu Ito; Hirohide Ito; Teruo Matsuura
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 271 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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Unirnolecular dissociation of Arz into Ari was investigated with a double focusing sector field mass spectrometer. Ar; was produced by electron impact ionization of Ar3 formed by nozzle expansion. It was found that the m&stable dissociation rate is strongly dependent on the sragnation gas temperatur
## Abstract The reversible __cis__/__trans__ photoisomerization of secondary thiopeptide bonds has been systematically studied with UVβvisible absorption, capillary electrophoresis, ^1^H NMR spectroscopy, and circular dichroism methods. It was found that the concentration of the __cis__ conformers