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Direct and sensitized cis—trans photoisomerization of 2-styrylthiophene

✍ Scribed by L.L. Costanzo; S. Pistarà; G. Condorelli; G. Scarlata

Publisher
Elsevier Science
Year
1977
Weight
573 KB
Volume
7
Category
Article
ISSN
0047-2670

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## Upon sensitized photoisomerization of cis-cyclooctene, aromatic esters possessing electron-withdrawing group(s) gave unusually high photostationary tram/& ratios up to 0.6. This is an improved photochemical route for preparing the highly strained truns isomer. ## We have demonstrated that the