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Direct measurement of the reaction rate for cis → trans photoisomerization of stilbene
✍ Scribed by Minoru Sumitani; Nobuaki Nakashima; Keitaro Yoshihara
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 313 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0009-2614
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Coherent low frequency ( 100-125 cm -~ ) nuclear motion was detected in the cis -~ trans condensed phase isomerization of stilbene. A mode, associated with phenyl torsional motion, has a vibrational dephasing time of 100 fs and exhibits solventdependent wavepacket dynamics. Selective probe wavelengt
The rate c&Want and the product distriblition for the reaction of D; w&h I& has been masured as a function of the Dz vibrational energy. in these experiments a mass analyzed bfzam of D3 ions is de&crated to le& than 0.1 eV and is subsequently injected into an ion cyclotron resonance (ICR) cell where