In the title compound, [Ru(C 4 H 3 N 2 S) 2 (C 18 H 15 P) 2 ]ÁCHCl 3 , the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecularinteractions between the pyrimidine and
✦ LIBER ✦
trans-Bis(6-methyl-2-pyridinolato)bis(triphenylphosphine)ruthenium(II)
✍ Scribed by Clegg, W. ;Berry, M. ;Garner, C. D.
- Book ID
- 114527409
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 310 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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The title compound, [Zn(C 6 H 15 N 3 ) 2 ](ClO 4 ) 2 , is a mononuclear Zn II complex of the restricted facial chelating ligand 6-amino-6-methylperhydro-1,4-diazepine (AAZ). The complex shows C 2h point symmetry, with two AAZ ligands bound to the hexacoordinated metal centre.