trans-Bis[(+)-(1R,4R)-3-benzoylcamphorato-κ2O,O′]copper(II)
✍ Scribed by Seo, Jang Woo ;Niemeyer, Mark
- Book ID
- 104487169
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 160 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
trans-Bis
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.038 wR factor = 0.106 Data-to-parameter ratio = 13.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Cu(C~4~H~3~O~4~)~2~(C~6~H~6~N~2~O)~2~], the Cu^II^ atom lies on a centre of symmetry and adopts a 4+2 elongated octahedral geometry with two hydrogen maleate ligands in axial positions. The complex molecules are linked __via__ N—H...O hydrogen bonds into a two-dimensional net
In the mononuclear title complex, [Cu(C 10 H 8 BrN 2 O 2 ) 2 ], the Cu atom, which lies on a centre of symmetry, is in a squareplanar geometry defined by a trans-N 2 O 2 donor set.