trans-2-Dimethylamino-3-p-nitrophenyl-1,4-diphenyl-3,4-dihydro-1-azetium perchlorate
β Scribed by Lindley, P. F. ;Walton, A. R. ;Boyd, G. V. ;Nicolaou, G. A.
- Book ID
- 114505343
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 407 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
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## Abstract 1,4βDihydroβ1,4βdiphenylβ2,3βbenzodithiin (**3**), synthesized from 1,2βbis(phenylmethyl)benzene (**1**), was subjected to oxidation to give 1,4βdihydroβ1,4βdiphenylβ2,3βbenzodithiin 2βoxide (**4**) as a mixture of diastereomers separable by column chromatography. (1R\*,2R\*,4S\*)β1,4βD
In the title compound, C 17 H 16 N 2 O 3 , the dihedral angle between the benzene rings is 1.56 (7) . The nitro group is coplanar with the attached benzene ring while the dimethylamino group is twisted slightly away from the attached benzene ring. A weak intramolecular C-HΓ Γ ΓO hydrogen bond is pre