2,3-Dihydro-5,7-diphenyl-1,4-diazepinium perchlorate hemihydrate
โ Scribed by Lloyd, D. ;Ferguson, G. ;Ruhl, B. L.
- Book ID
- 114507970
- Publisher
- International Union of Crystallography
- Year
- 1991
- Tongue
- English
- Weight
- 467 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
N-Unsubstituted 2,3-dihydro-1,4-diazepinium salts 4 a -d are N-methylated readily (-5ad) by using iodomethane and potassium carbonate in dimethylformamide. The 2,3dihydro-5,7-diphenyl-I ,4-diazcpinium salt 4 d could be N-ethylated but not N-isopropylated, presumably for steric reasons. Vicinal crowd
2,3-Dihydro-6-(4-hydroxyphenyl)-l,4-diazepinium salts 3a, b are readily mono-(+ 4a, b) and di-brominated (+ 5a, b) at the rneta-postion of the phenyl substituent. 2,3-Dihydro-6-(3hydroxyphenyl)-l,4-diazepinium salts 6a, b are readily mono-brominated (+ 7a, b) at the para-position of the phenyl subst