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Towards the synthesis of pristinamycin PIIA; preparation of the optically pure C-3/C-7 fragment

✍ Scribed by N. Adjé; P. Breuilles; D. Uguen


Book ID
103405066
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
264 KB
Volume
33
Category
Article
ISSN
0040-4039

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An enantioselective and convergent synthesis of the C7-C24 fragment of Macrolactin F was achieved from four main fragments. A hydrotelluration/transmetalation sequence was used to install the E,Z diene present in the molecule, while a hydrozirconation/transmetalation sequence was used to connect two