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Synthesis of the C7–C24 fragment of (−)-Macrolactin F

✍ Scribed by Roberta A. Oliveira; Juliana M. Oliveira; Luis H.S. Rahmeier; Joao V. Comasseto; Joseph P. Marino; Paulo H. Menezes

Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 163 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.07.113

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✦ Synopsis

An enantioselective and convergent synthesis of the C7-C24 fragment of Macrolactin F was achieved from four main fragments. A hydrotelluration/transmetalation sequence was used to install the E,Z diene present in the molecule, while a hydrozirconation/transmetalation sequence was used to connect two advanced intermediates.

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