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Toward the Total Synthesis of the Brasilinolides: Construction of a Differentially Protected C20−C38 Segment

✍ Scribed by Paterson, Ian; Burton, Paul M.; Cordier, Christopher J.; Housden, Michael P.; Mühlthau, Friedrich A.; Loiseleur, Olivier

Book ID
124167429
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
201 KB
Volume
11
Category
Article
ISSN
1523-7060

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Synthetic Studies towards Halichondrins:
Synthetic Studies towards Halichondrins: Synthesis of the C.27–C.38 Segment
✍ Thomas D. Aicher; Keith R. Buszek; Francis G. Fang; Craig J. Forsyth; Sun Ho Jun 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 277 KB

An efficient synthesis of the C.27-C.38 segment of halichondrins is accomplished, using the Ireland-Claisen rearrangement, Ni(ll)lCr(Il)-mediated coupling and Michael reactions as the key steps.