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Total Synthesis of Ustiloxin D and Considerations on the Origin of Selectivity of the Asymmetric Allylic Alkylation.

โœ Scribed by Andrew M. Sawayama; Hiroko Tanaka; Thomas J. Wandless


Publisher
John Wiley and Sons
Year
2005
Weight
11 KB
Volume
36
Category
Article
ISSN
0931-7597

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The effect of the natural bite angle (ฮฒ n ) of diphosphane li-angle of the ligand becomes larger. This results in an increasing selectivity at larger bite angles, but at very large gands on catalyst selectivity and activity in the palladiumcatalyzed allylic alkylation was investigated. The selectivi