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Total Synthesis of Thiostrepton, Part 2: Construction of the Quinaldic Acid Macrocycle and Final Stages of the Synthesis

✍ Scribed by K. C. Nicolaou; Mark Zak; Brian S. Safina; Sang Hyup Lee; Anthony A. Estrada

Book ID
101563893
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
429 KB
Volume
43
Category
Article
ISSN
0044-8249

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Total Synthesis of Thiostrepton, Part 2:
Total Synthesis of Thiostrepton, Part 2: Construction of the Quinaldic Acid Macrocycle and Final Stages of the Synthesis
✍ K. C. Nicolaou; Mark Zak; Brian S. Safina; Sang Hyup Lee; Anthony A. Estrada πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 428 KB πŸ‘ 1 views

In the preceding Communication in this issue [1] we described the construction of the thiazoline-containing macrocycle 2 as an advanced intermediate toward the total synthesis of thiostrepton (1). Herein we report the construction of suitable dipeptide (8, Scheme 1) and quinaldic acid (22, Scheme 2)