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Total Synthesis of the Proposed Structures of Indole Alkaloids Lyaline and Lyadine.

✍ Scribed by M.-Lluisa Bennasar; Tomas Roca; Manuel Monerris


Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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Total Synthesis of the Indole Alkaloid V
✍ Priv.-Doz. Dr. Dietrich Spitzner; Prof. Dr. Ernest Wenkert πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 213 KB πŸ‘ 2 views

The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc