Total synthesis of the polyenoyltetramic
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Deborah A Longbottom; Angus J Morrison; Darren J Dixon; Steven V Ley
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Article
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2003
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Elsevier Science
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French
โ 325 KB
The total synthesis of the polyenoyltetramic acid polycephalin C is described. Key steps of the synthesis include a double Swern oxidation, double Takai reaction and a double Stille reaction. In addition, the absolute stereochemistry of the ring junction has been determined by synthesis of both isom