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Total synthesis of the Fusarium toxin equisetin: proof of the stereochemical relationship of the tetramate and terpenoid sectors

✍ Scribed by Turos, Edward; Audia, James E.; Danishefsky, Samuel J.

Book ID
111889989
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
798 KB
Volume
111
Category
Article
ISSN
0002-7863

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Recent synthetic and degradative studies (1) have necessitated a structural revision of the entire class of vetivane sesquiterpenes whereby the previously accepted bicycIoC5.3.01decane carbon framework (I) must be discarded in favor of the spiroC4. Sldecane system (II).