Stereochemical relationships in spirovetivane sesquiterpenes: The total synthesis of hinesol
β Scribed by James A. Marshall; Stephen F. Brady
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 220 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
Recent synthetic and degradative studies (1) have necessitated a structural revision of the entire class of vetivane sesquiterpenes whereby the previously accepted bicycIoC5.3.01decane carbon framework (I) must be discarded in favor of the spiroC4. Sldecane system (II).
π SIMILAR VOLUMES
x\_~xxxx\_ A total synthesis of B-cuparenone, which highlights the advantages and disadvantages of the three-carbon annulation process, is described. The cyclopentane ring system is found in numerous naturally occurring products, including such diverse compounds as steroids, prostaglandins, and terp
## Double Diastereoselection in Intramolecular Photocycloadditions: A Radical Rearrangement Approach to the Total Synthesis of the Spirovetivane Phytoalexin (Β±)-Lubiminol. -Key steps in the synthesis of the title compound (XIII) are a conjugate addition-cyclization reaction to prepare compound (I
## Abstract Review: ca. 100 refs.