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Total synthesis of the Fusarium toxin equisetin

✍ Scribed by Burke, Lisa T.; Dixon, Darren J.; Ley, Steven V.; Rodr�guez, F�lix


Book ID
120458120
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
211 KB
Volume
3
Category
Article
ISSN
1477-0520

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Two alternative synthetic routes of the left-half segment 5 have been developed. Efficient condensation between the left and right segments followed by Pd-catalyzed deoxygenation and further elaboration achieved the first total synthesis of AAL-toxin TAI. This allowed us to synthesize various AAL-to