Total synthesis of (±)-pterocarpin and (±)-pisatin
✍ Scribed by Kenji Fukui; Mitsuru Nakayama
- Book ID
- 104250253
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 149 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Asymmetric Total Synthesis of (+)-Pisatin, a Phytoalexin from Garden Peas (Pisum sativum L.). -Based on a modified Sharpless asymmetric dihydroxylation of the 2H-1-benzopyran (II) and following hydrogenenative cyclization, a short asymmetric total synthesis of (+)-pisatin (VI) is realized. -(
Thc first synthesis of (-)-pterocarpin (6) was achieved by rcsolving (\*)-2, which in turn was prepared from a known isonavone (1). Unnatural (+ tpterocarpin was also synthesized. (-)-Pterocarpin (6) was first isolated by Cazeneuve in 1874 as a constituent of red sandalwood, Pterocarpus suntalinus