ChemInform Abstract: Asymmetric Total Sy
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E. PINARD; M. GAUDRY; F. HENOT; A. THELLEND
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Article
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2010
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John Wiley and Sons
⚖ 32 KB
Asymmetric Total Synthesis of (+)-Pisatin, a Phytoalexin from Garden Peas (Pisum sativum L.). -Based on a modified Sharpless asymmetric dihydroxylation of the 2H-1-benzopyran (II) and following hydrogenenative cyclization, a short asymmetric total synthesis of (+)-pisatin (VI) is realized. -(