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Asymmetric total synthesis of (+)-pisatin, a phytoalexin from garden peas (Pisum sativum L.)

✍ Scribed by Emmanuel Pinard; Michel Gaudry; Frédéric Hénot; Annie Thellend


Book ID
108386633
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
207 KB
Volume
39
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Asymmetric Total Sy
✍ E. PINARD; M. GAUDRY; F. HENOT; A. THELLEND 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Asymmetric Total Synthesis of (+)-Pisatin, a Phytoalexin from Garden Peas (Pisum sativum L.). -Based on a modified Sharpless asymmetric dihydroxylation of the 2H-1-benzopyran (II) and following hydrogenenative cyclization, a short asymmetric total synthesis of (+)-pisatin (VI) is realized. -(