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ChemInform Abstract: Asymmetric Total Synthesis of (+)-Pisatin, a Phytoalexin from Garden Peas (Pisum sativum L.).

✍ Scribed by E. PINARD; M. GAUDRY; F. HENOT; A. THELLEND

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199829297

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✦ Synopsis

Asymmetric Total Synthesis of (+)-Pisatin, a Phytoalexin from Garden Peas (Pisum sativum L.).

-Based on a modified Sharpless asymmetric dihydroxylation of the 2H-1-benzopyran (II) and following hydrogenenative cyclization, a short asymmetric total synthesis of (+)-pisatin (VI) is realized. -(

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