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Total Synthesis of (+)-Octalactins A and B: Unusual Metabolites from a Marine Microbe

โœ Scribed by McWilliams, J. Chris; Clardy, Jon

Book ID
121224113
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
245 KB
Volume
116
Category
Article
ISSN
0002-7863

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Studies towards the synthesis of the marine metabolite octalactin A 1, are described. Key steps in this strategy include an anti aldol reaction to set the C7-Cs stere~ehemisla'y, Homer Wadsworth Ernmom coupling to give the trisubstituted E-double bond and a novel samarinm-mediated cyclisation reacti