✦ LIBER ✦

Total synthesis of myriocin

✍ Scribed by Kee-Young Lee; Chang-Young Oh; Yong-Hyun Kim; Jae-Eun Joo; Won-Hun Ham

Book ID: 104252500
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 211 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02371-7

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✦ Synopsis

A concise, stereocontrolled synthesis of myriocin was achieved. Key features involve diastereoselective oxazoline formation catalyzed by palladium(0), MgBr 2 -promoted allylic stannane addition, and palladium(0)-catalyzed coupling of a vinyl iodide with an organozinc reagent.

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