𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Total synthesis of methyl picrotoxate via the palladium catalyzed enyne cycloisomerization reaction

✍ Scribed by Michael J. Krische; Barry M. Trost

Book ID
104208476
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
765 KB
Volume
54
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis

Abstmct: Bifurcation of the synthetic pathway affording total syntheses of picrotoxinin, picrotin and corianin from a common synthetic intermediate daived via the palladium catalyzed enyne cycloisomerization leads to the total synthesis of the picrotoxane sesquiterpene methyl picrotoxate.

πŸ“œ SIMILAR VOLUMES

Total synthesis of 7-O-methyldehydroping
Total synthesis of 7-O-methyldehydropinguisenol by palladium–catalyzed 1,7-enyne cycloisomerization
✍ Kenichi Harada; Yasutoshi Tonoi; Hiroaki Kato; Yoshiyasu Fukuyama πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 66 KB

Efficient synthesis of 7-O-methyldehydropinguisenol, a typical pinguisane-type sesquiterpene with a furan moiety, was accomplished by applying palladium-catalyzed 1,7-enyne cycloisomerization for the construction of six-membered ring bearing an exomethylene as well as of adjacent quaternary centers.

ChemInform Abstract: Synthesis of Functi
ChemInform Abstract: Synthesis of Functionalized Carbo- and Heterocycles via Gold-Catalyzed Cycloisomerization Reactions of Enynes.
✍ Lucie Leseurre; Chung-Meng Chao; Tomohiro Seki; Emilie Genin; Patrick Y. Toullec πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons βš– 57 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v