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Total synthesis of 7-O-methyldehydropinguisenol by palladium–catalyzed 1,7-enyne cycloisomerization

✍ Scribed by Kenichi Harada; Yasutoshi Tonoi; Hiroaki Kato; Yoshiyasu Fukuyama

Book ID
104251092
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
66 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Efficient synthesis of 7-O-methyldehydropinguisenol, a typical pinguisane-type sesquiterpene with a furan moiety, was accomplished by applying palladium-catalyzed 1,7-enyne cycloisomerization for the construction of six-membered ring bearing an exomethylene as well as of adjacent quaternary centers.

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