The first synthesis of ( +)-crocacin C (3) in optically pure form is achieved following a convergent strategy. The synthesis also establishes the absolute stereochemistries of this novel class of potent antifungal and highly cytotoxic compounds. The naturally occurring crocacin C has (6S,7S,8R,9S) c
Total synthesis of (−)-betaenone C
✍ Scribed by Akitami Ichihara; Shokyo Miki; Hirokazu Kawagishi; Sadao Sakamura
- Book ID
- 104233184
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 244 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Stereoselective synthesis of (-)-betaenone C through intramolecular Diels-Alder reaction has trade pssible to provide pertinent intermediates for the biosynthetic study of betaenones.
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