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Total synthesis of (+)-crocacin C

✍ Scribed by Tushar K Chakraborty; Sarva Jayaprakash

Book ID: 104211546
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 85 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)02002-5

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✦ Synopsis

The first synthesis of ( +)-crocacin C (3) in optically pure form is achieved following a convergent strategy. The synthesis also establishes the absolute stereochemistries of this novel class of potent antifungal and highly cytotoxic compounds. The naturally occurring crocacin C has (6S,7S,8R,9S) configuration, which is also the same for other congeners of the family, crocacins A, B and D.

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