Total synthesis of balanol, part 1. Enantioselective synthesis of the hexahydroazepine ring via chiral epoxides and aziridines
✍ Scribed by David Tanner; Antonio Almario; Thomas Högberg
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 655 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Wittig ring contraction of the achiral 13-membered acetylenic ether 1 via treatment with lithio (R,R) or (S,S)-his-(1-phenylethyl)amide afforded the (RI-( +) or (S)-(-)-propargylic alcohol (+ J-2 or (-1-2, respectively, of >60% ee in 75% yield.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Asymmetric one-pot aziridination of imines with alkyl bromides via the imino Corey-Chaykovsky reaction mediated by chiral sulfide is described. The desired aziridines are obtained in good yields with up to 98% ee of the trans isomer.