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Enantioselective synthesis of aziridines from imines and alkyl halides using a camphor-derived chiral sulfide mediator via the imino Corey–Chaykovsky reaction

✍ Scribed by Takao Saito; Masao Sakairi; Daisuke Akiba

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 61 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01016-4

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✦ Synopsis

Asymmetric one-pot aziridination of imines with alkyl bromides via the imino Corey-Chaykovsky reaction mediated by chiral sulfide is described. The desired aziridines are obtained in good yields with up to 98% ee of the trans isomer.

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