𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Total synthesis of asterriquinone B1

✍ Scribed by Kun Liu; Harold B. Wood; A.Brian Jones


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
194 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


This communication describes the first total synthesis of asterriquinone B 1, a representative member of a group of anti-tumor metabolites of Aspergillus terreus. The synthesis described herein is potentially applicable to other members of the asterriquinone family.


πŸ“œ SIMILAR VOLUMES


Total synthesis of antibiotic karnamicin
✍ Kazuyuki Umemura; Koichi Watanabe; Kazumasa Ono; Masanori Yamaura; Juji Yoshimur πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 177 KB

The novel antifungal karnamicin B, (1), 5-hydroxy-3,4-dimethoxy-2-(2-(4-oxopentyl)-4-thiazolyl}pyridine-6-carboxamide was first synthesized via the formation of partially methylated trihydroxy pyridine by ring-transformation from the corresponding furan derivative and subsequent regioselective intro

Total Synthesis of Piericidin A1 and B1.
✍ Martin J. Schnermann; Dale L. Boger πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 11 KB πŸ‘ 2 views
A facile synthesis of asterriquinone D
✍ Yasuhiro Tanoue; Takashi Motoi; Yutaka Masuda; Norihisa Kai; Kazunori Sakata; Ma πŸ“‚ Article πŸ“… 2008 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 229 KB

## Abstract magnified image Asterriquinone D was easily synthesized in three steps from 2,5‐dichloro‐1,4‐benzoquinone. The reaction of benzoquinone with indole in the presence of Pd(OAc)~2~, followed by oxidation with cerium (IV) ammonium nitrate (CAN) produced 3,6‐dichloro‐2,5‐bis (3‐indolyl)‐1,4