Total enantiospecific syntheses of 13(S)-hydroxy 9Z, 11E-octadecadienoic (coriolic) acid and 13(S)-N-tosylamino analogue
✍ Scribed by I. Tranchepain; F. Le Berre; A. Duréault; Y. Le Merrer; J.C. Depezay
- Book ID
- 108371515
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 571 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0040-4020
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## Abstract The asymmetric __Sharpless__ epoxidation of methyl 13__S__‐hydroxy‐9__Z__, 11__E__‐octadeca‐dienoate (13__S__‐HODE, **1**) with __tert__‐butyl hydroperoxide (TBHP) catalysed by titanium tetraisopropoxide {Ti(^__i__^OPr)~4~} in the presence of L(+)‐diisopropyl tartrate (L‐DIPT) gave meth
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