In the presence of oxygen, UV-irradiation of a solution of methyl 13(S)-hydroperoxy-9(Z), 1 l(E)-octadecadienoate (13-HPOD) in cyclohexane leads to a broad pattern of reaction products of which a trihydroxyene, seven epoxyhydroxides, four hydroxydienes, four epoxyhydroperoxides, six oxodienes and an
Conversion of 13(S)-hydroperoxy-9(Z),11(E)-octadecadienoic acid to the corresponding hydroxy fatty acid by KOH: A kinetic study
โ Scribed by Thomas D. Simpson; Harold W. Gardner
- Book ID
- 112774226
- Publisher
- Springer-Verlag
- Year
- 1993
- Tongue
- English
- Weight
- 670 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0024-4201
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๐ SIMILAR VOLUMES
A solution of methyl 13(S)-hydroperoxy-9(Z),ll(E)-octadecadienoate (13-HPOD)in methanol was irradiated under anaerobic conditions at 15ยฐC with light at wavelengths greater than 230 nm. After 2 h the 13-HPOD was completely degraded and four major products were formed. Three of them were identified as
in the presence of oxygen, UV-irradiation of a solution of methyl 13(S)-hydroperoxy-9(Z),l I(E)octadecadienoate (13-HPOD) in methanol yields stereoisomers of methyl 9,13-dihydroxy-10methoxy-1 l(E)-octadecenoate and methyl 9,13-dihydroxy-12-methoxy-10(E)-octadecenoate as major products. The reaction