Topotactic reactions of the molybdenum chalcogenide phase In2Mo15Se19
β Scribed by C. Boulanger; B. El Mehdi; J.M. Lecuire
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 418 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0167-2738
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π SIMILAR VOLUMES
The insertion/de-insertion topotactic reactions in the Chevrel-type molybdenum cluster chalcogenides Mo6Xs (X = S, Se) are studied in the potentiodynamic mode on crystallite bed electrodes. We define the best conditions for the identification of the successive steps of the insertion (M,Mo,Xs). The p
## Abstract For Abstract see ChemInform Abstract in Full Text.
In the literature Mo 6 Se 8Ψx S x (04x44) Chevrel phase binaries are stable compounds, synthesized by solid state reaction from stoichiometric mixture of MoS 2 , MoSe 2 , and Mo powders at 12003C. We report the single-crystal structure of these compounds. The structural determinations show as expect