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Syntheses and Crystal Structures of the Compounds In3.7Mo15S19, In1.6Rb2Mo15S19, In2.2CsMo15S19 and ScTl2Mo15S19 Containing Mo6 and Mo9 Clusters.

✍ Scribed by Diala Salloum; Patrick Gougeon; Thierry Roisnel; Michel Potel

Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê