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Molybdenum cluster chalcogenide electrochemistry—I. Potentiodynamic study of topotactic insertion reactions

✍ Scribed by C. Boulanger; J.M. Lecuire

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
376 KB
Volume
33
Category
Article
ISSN
0013-4686

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✦ Synopsis

The insertion/de-insertion topotactic reactions in the Chevrel-type molybdenum cluster chalcogenides Mo6Xs (X = S, Se) are studied in the potentiodynamic mode on crystallite bed electrodes. We define the best conditions for the identification of the successive steps of the insertion (M,Mo,Xs). The phenomenon of the cation diffusion in the host lattice is responsible for the voltamperogram features.

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