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Toluene Combustion: Reaction Paths, Thermochemical Properties, and Kinetic Analysis for the Methylphenyl Radical + O 2 Reaction

โœ Scribed by da Silva, Gabriel; Chen, Chiung-Chu; Bozzelli, Joseph W.


Book ID
126179826
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
353 KB
Volume
111
Category
Article
ISSN
1089-5639

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Chemical activation and unimolecular dissociation pathway kinetic analysis is presented on addition of radicals H, O, OH, and HO 2 to one of the two types of unsaturated carbons on cyclopentadiene. Addition of H atom or OH radical at the 1 position forms an allylic radical, which can break the weake