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Thermochemical and Kinetic Analysis of the Acetyl Radical (CH 3 C • O) + O 2 Reaction System

✍ Scribed by Lee, Jongwoo; Chen, Chiung-Ju; Bozzelli, Joseph W.

Book ID
126998688
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
245 KB
Volume
106
Category
Article
ISSN
1089-5639

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✍ Edit Farkas; Gergely Kovács; István Szilágyi; Sándor Dóbé; Tibor Bérces; Ferenc 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 1 views

## Abstract The fast flow method with laser induced fluorescence detection of CH~3~C(O)CH~2~ was employed to obtain the rate constant of __k__~1~ (298 K) = (1.83 ± 0.12 (1σ)) × 10^10^ cm^3^ mol^−1^ s^−1^ for the reaction CH~3~C(O)CH~2~ + HBr ↔ CH~3~C(O)CH~3~ + Br (1, −1). The observed reduced react