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Thermochemical and Kinetic Analysis of the H, OH, HO2, O, and O2 Association Reactions with Cyclopentadienyl Radical

โœ Scribed by Zhong, Xian; Bozzelli, Joseph W.


Book ID
111871262
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
643 KB
Volume
102
Category
Article
ISSN
1089-5639

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โœ Xian Zhong; Joseph W. Bozzelli ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 349 KB ๐Ÿ‘ 2 views

Chemical activation and unimolecular dissociation pathway kinetic analysis is presented on addition of radicals H, O, OH, and HO 2 to one of the two types of unsaturated carbons on cyclopentadiene. Addition of H atom or OH radical at the 1 position forms an allylic radical, which can break the weake

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The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u