## 1998 sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600 ## 47 -098 Toluene and Naphthalene Dioxygenase-Catalyzed Sulfoxidation of Alkyl Aryl Sulfides. -A series of alkyl sulfides (I) and (III) are metabolized, using select
Toluene and naphthalene dioxygenase-catalysed sulfoxidation of alkyl aryl sulfides
β Scribed by Boyd, Derek R.; Sharma, Narain D.; Haughey, Simon A.; Kennedy, Martina A.; McMurray, Brian T.; Sheldrake, Gary N.; Allen, Christopher C. R.; Dalton, Howard; Sproule, Kenneth
- Book ID
- 119995906
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Weight
- 102 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1472-7781
- DOI
- 10.1039/A801515E
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π SIMILAR VOLUMES
Chlorophenyl alkyl sulfides are mono-arylated and -alkylated selectively with Grignard reagents, in the presence of Ni(PPh3)2C12, to give aryl-and alkyl-phenyl alkyl sulfides.
## Abstract Enantioselective vanadiumβcatalysed oxidation of aryl benzyl sulfides using Bolmβs procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90β% __ee__), albeit with an associat