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ChemInform Abstract: Toluene and Naphthalene Dioxygenase-Catalyzed Sulfoxidation of Alkyl Aryl Sulfides.

✍ Scribed by D. R. BOYD; N. D. SHARMA; S. A. HAUGHEY; M. A. KENNEDY; B. T. MCMURRAY; G. N. SHELDRAKE; C. C. R. ALLEN; H. DALTON; K. SPROULE

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998

sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600

47 -098

Toluene and Naphthalene Dioxygenase-Catalyzed Sulfoxidation of Alkyl Aryl Sulfides.

-A series of alkyl sulfides (I) and (III) are metabolized, using selected strains of the soil bacterium P. putida containing either toluene dioxygenase (UV4) or naphthalene dioxygenase (NCIMB 8859), to give chiral sulfoxides. In some cases enantiocomplementary is observed, cf. (Ia). The stereoselectivity appears to be mainly dependant on enzyme-catalyzed asymmetric sulfoxidation rather than on kinetic resolution. -(BOYD, D. R.;

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