Selective mono-arylation and -alkylation of chlorophenyl alkyl sulfides by nickel catalysed cross-coupling with grignard reagents

✍ Scribed by Marcello Tiecco; Lorenzo Testaferri; Marco Tingoli; Donatella Chianelli; Ernest Wenkert

• Publisher: Elsevier Science
• Year: 1982
• Tongue: French
• Weight: 210 KB
• Volume: 23
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)85672-5

✦ Synopsis

Chlorophenyl alkyl sulfides are mono-arylated and -alkylated selectively with Grignard reagents, in the presence of Ni(PPh3)2C12, to give aryl-and alkyl-phenyl alkyl sulfides.