## Abstract The titanocene(III) chloride mediated opening of silyloxiranes has been examined. Electron transfer from the metal leads to __Ξ±__βsilyl radicals with total regiocontrol. The radicals could be trapped by various olefins, and the corresponding adducts were obtained in good yields (__Table
Titanocene-Mediated Homolytic Opening of Epoxysilanes.
β Scribed by Nicolas Puljic; Matthias Albert; Anne-Lise Dhimane; Louis Fensterbank; Emmanuel Lacote; Max Malacria
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 28 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
π SIMILAR VOLUMES
## Abstract Electrocatalytic opening of styrene oxides (I) furnishing the corresponding primary alcohols (II) is accomplished using electrochemically reduced titanocene dichloride as catalyst, TmsCl as reagent for TiβO bond cleavage and 1,4βcyclohexadiene as Hβatom donor to prevent side reactions.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.