Titanocene-Catalysed Electron Transfer-Mediated Opening of Epoxides
✍ Scribed by Andreas Gansäuer; Sanjay Narayan
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 189 KB
- Volume
- 344
- Category
- Article
- ISSN
- 1615-4150
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📜 SIMILAR VOLUMES
## Abstract Electrocatalytic opening of styrene oxides (I) furnishing the corresponding primary alcohols (II) is accomplished using electrochemically reduced titanocene dichloride as catalyst, TmsCl as reagent for Ti‐O bond cleavage and 1,4‐cyclohexadiene as H‐atom donor to prevent side reactions.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract The titanocene(III) chloride mediated opening of silyloxiranes has been examined. Electron transfer from the metal leads to __α__‐silyl radicals with total regiocontrol. The radicals could be trapped by various olefins, and the corresponding adducts were obtained in good yields (__Table
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v