Titanocene-Catalyzed Regiodivergent Epoxide Openings.
β Scribed by Andreas Gansaeuer; Chun-An Fan; Florian Keller; Jutta Keil
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 40 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Dramatic Rate Acceleration in Titanocene Catalyzed Epoxide Openings: Cofactors and Lewis Acid Cocatalysis. -The titanocene catalyzed addition reaction of epoxides like (I) to Ξ±,Ξ²-unsaturated carbonyl compounds can be improved by Lewis acid cocatalysis, cf. conditions A or by hydrogen bonding with c